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Chitosan

HMC eigen-0509-005

Chemical name:
(1,4)-2-Amino-2-desoxy- beta-D-glucan
Empirical formula:
(C6H11NO4)n
CAS 9012-76-4

Chitosan differs from chitin in that it has free amino groups (figure 1) and is obtained by deacetylizing chitin. At a minimum deacetylization level of 70% (=amount of free amino groups in the polymer) it is considered to be chitosan. The monomer of chitosan is D-amino glucose.

chitosan-chemie

Manufacturing process

During the deacetylization process, chitin undergoes a treatment with lye to divide the acetyl groups from the polymer, resulting in chitosan. This has a variation of properties depending on the degree of deacetylization and chain length.

Solubility

  • soluble in nearly all diluted acids
  • insoluble in sulfuric acid and water
  • not thermo-elastic, decomposes at 280° C
  • pKa 6.3

Properties of cationic polymer chitosan include:

  • high charge carrier density
  • biodegradable, non-toxic
  • bacteriostatic, fungistatic
  • film and fiber forming, cross-linking
  • immobilization of living organisms
  • anti-inflammatory, heals wounds
  • stimulation of immune system and metabolism
  • deodorizing
  • bonding ability to proteins, heavy metals and aerosols

Biodegradability:

Biodegradable through naturally occurring enzymes